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印度拉贾斯坦邦凯特里铜矿尾矿及周边土壤中金属污染的来源与评估

Source and Assessment of Metal Pollution at Khetri Copper Mine Tailings and Neighboring Soils, Rajasthan, India.

作者信息

Punia Anita, Siddaiah N Siva, Singh Saurabh K

机构信息

School of Environmental Sciences, Jawaharlal Nehru University, New Delhi, 110 067, India.

出版信息

Bull Environ Contam Toxicol. 2017 Nov;99(5):633-641. doi: 10.1007/s00128-017-2175-6. Epub 2017 Sep 27.

Abstract

We present here the results of the study on metal pollution by identifying source, abundance and distribution in soil and tailings of Khetri copper complex (KCC) mines, Rajasthan India. The region is highly contaminated by copper (Cu) with higher values in the soil near overburden material (1224 mg/kg) and tailings (111 mg/kg). The average Cu (231 mg/kg) concentration of soil is ~9, 5 and 32 times higher than upper crust, world average shale (WAS) and local background soil (LS), respectively. However this reaches to ~82, 46 and 280 times higher in case of tailing when compared. The correlation and principal component analysis for soil reveals that the source of Cu, Zn, Co, Ni, Mn and Fe is mining and Pb and Cd could be result of weathering of parent rocks and other anthropogenic activities. The source for Cr in soil is both mining activities and weathering of parent rocks. The values of index of geo-accumulation (I) and pollution load index for soil using LS as background are higher compared to values calculated using WAS. The metal rich sulphide bearing overburden material as well as tailings present in the open environment at KCC mines region warrants a proper management to minimize their impact on the environment.

摘要

我们在此展示了一项关于印度拉贾斯坦邦科特里铜矿区(KCC)土壤和尾矿中金属污染的研究结果,该研究旨在确定金属的来源、丰度及分布情况。该地区铜(Cu)污染严重,覆盖层附近土壤中的铜含量较高(1224毫克/千克),尾矿中的铜含量为111毫克/千克。土壤中铜的平均浓度(231毫克/千克)分别比上地壳、世界平均页岩(WAS)和当地背景土壤(LS)高出约9倍、5倍和32倍。然而,相比之下,尾矿中的铜含量分别高出约82倍、46倍和280倍。土壤的相关性和主成分分析表明,铜、锌、钴、镍、锰和铁的来源是采矿活动,而铅和镉可能是母岩风化及其他人为活动的结果。土壤中铬的来源既有采矿活动,也有母岩风化。以LS为背景计算的土壤地累积指数(I)和污染负荷指数值,高于以WAS为背景计算的值。KCC矿区露天环境中富含金属的含硫化物覆盖层材料以及尾矿,需要进行妥善管理,以尽量减少其对环境的影响。

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