用于有机金属-有机杂化聚合物程序化合成的具有不稳定二磷配体的预组织化银双金属前体
Preorganized Ag Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers.
作者信息
Moussa Mehdi Elsayed, Seidl Michael, Balázs Gábor, Zabel Manfred, Virovets Alexander V, Attenberger Bianca, Schreiner Andrea, Scheer Manfred
机构信息
Institut für Anorganische Chemie, Universität Regensburg, 93040, Regensburg, Germany.
Nikolaev Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev str. 3, 630090, Novosibirsk, Russia.
出版信息
Chemistry. 2017 Nov 16;23(64):16199-16203. doi: 10.1002/chem.201704582. Epub 2017 Oct 25.
An Ag dimer capped with labile organometallic diphosphorus ligands [Cp Mo (CO) (η -P )] (Cp=C H ) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.
一种由不稳定的有机金属二磷配体[CpMo(CO)(η -P)]（Cp = C₅H₅）封端的银二聚体，在与双齿吡啶基连接体反应时，作为一种高度预组织的分子前体，可指导一维、二维和三维有机金属-有机杂化配位聚合物的构建。超分子聚集体的形成可通过有机分子的化学计量比来控制，且该机理得到了密度泛函理论计算的支持。
Zotero 插件