Moussa Mehdi Elsayed, Welsch Stefan, Lochner Matthias, Peresypkina Eugenia V, Virovets Alexander V, Scheer Manfred
Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg Germany.
Nikolaev Institute of Inorganic Chemistry Siberian Division of RAS Lavrentyev prosp. 3 630090 Novosibirsk Russia.
Eur J Inorg Chem. 2018 Jun 22;2018(23):2689-2694. doi: 10.1002/ejic.201800112. Epub 2018 Jun 11.
A multicomponent approach of the P ligand complex [CpFe(η-P)] (: Cp = η-CMe) with the ditopic organic linkers 4,4'-bipyridine () or -1,2-di(pyridine-4-yl)ethene () in the presence of Cu salts of the anions [BF] and [PF] or the coordinating anion Br, leads to the formation of four novel organometallic-organic hybrid polymers: the cationic 1D polymeric compounds [Cu{CpFe(µ,η-P)}(µ,η-CHN)(CHCN)] [BF] () and [Cu{CpFe(µ,η-P)}(µ,η-CHN)(CHCN)] [PF] () as well as the unique neutral threefold 2D → 2D interpenetrated networks [CuCl{CpFe(µ,η-P)}(µ,η-CHN)] () and [CuBr{CpFe(µ,η-P)}(µ,η-CHN)] ().
在阴离子[BF]和[PF]的铜盐或配位阴离子Br存在下，P配体配合物[CpFe(η-P)]（：Cp = η-CMe）与双位点有机连接体4,4'-联吡啶（）或-1,2-二（吡啶-4-基）乙烯（）采用多组分方法，导致形成四种新型有机金属-有机杂化聚合物：阳离子一维聚合化合物[Cu{CpFe(µ,η-P)}(µ,η-CHN)(CHCN)] [BF]（）和[Cu{CpFe(µ,η-P)}(µ,η-CHN)(CHCN)] [PF]（）以及独特的中性三重二维→二维互穿网络[CuCl{CpFe(µ,η-P)}(µ,η-CHN)] （）和[CuBr{CpFe(µ,η-P)}(µ,η-CHN)] （）。
