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关于畸变定理的一则注释。

A note on the distortion theorem.

作者信息

Nickolsky M S

机构信息

Institute of Ore Deposits, Mineralogy, Petrography and Geochemistry, Staromonetny, 35, Moscow, 119017, Russian Federation.

出版信息

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017 Oct 1;73(Pt 5):874-878. doi: 10.1107/S205252061700912X. Epub 2017 Sep 15.

Abstract

The distortion theorem is a conditional statement that establishes the certain relations between the variation of the mean bond length and the variation of the valence of a central ion of a coordination polyhedron. It was found that in some principal cases the conditional part of the distortion theorem is not necessary. A combinatorial evaluation of the distortion theorem and a theoretical analysis of the bond length-bond valence correlation were performed. An extension of the distortion theorem is proposed.

摘要

畸变定理是一个条件陈述,它确立了平均键长的变化与配位多面体中心离子价态变化之间的特定关系。研究发现,在某些主要情况下,畸变定理的条件部分并非必要。对畸变定理进行了组合评估,并对键长-键价相关性进行了理论分析。提出了畸变定理的一个扩展。

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