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基于导电聚(3,4-亚乙基二氧噻吩)-聚(苯乙烯磺酸盐)聚合物复合物的用于纺织增强热塑性复合材料的原位结构健康监测的新型纺织传感器。

New Textile Sensors for In Situ Structural Health Monitoring of Textile Reinforced Thermoplastic Composites Based on the Conductive Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) Polymer Complex.

机构信息

Department of Textile Chemistry and Ecology, University of Zagreb Faculty of Textile Technology, 10000 Zagreb, Croatia.

Ecole Nationale Supérieure des Arts et Industries Textiles, GEMTEX Laboratory, 59056 Roubaix, France.

出版信息

Sensors (Basel). 2017 Oct 10;17(10):2297. doi: 10.3390/s17102297.

Abstract

Many metallic structural and non-structural parts used in the transportation industry can be replaced by textile-reinforced composites. Composites made from a polymeric matrix and fibrous reinforcement have been increasingly studied during the last decade. On the other hand, the fast development of smart textile structures seems to be a very promising solution for in situ structural health monitoring of composite parts. In order to optimize composites' quality and their lifetime all the production steps have to be monitored in real time. Textile sensors embedded in the composite reinforcement and having the same mechanical properties as the yarns used to make the reinforcement exhibit actuating and sensing capabilities. This paper presents a new generation of textile fibrous sensors based on the conductive polymer complex poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) developed by an original roll to roll coating method. Conductive coating for yarn treatment was defined according to the preliminary study of percolation threshold of this polymer complex. The percolation threshold determination was based on conductive dry films' electrical properties analysis, in order to develop highly sensitive sensors. A novel laboratory equipment was designed and produced for yarn coating to ensure effective and equally distributed coating of electroconductive polymer without distortion of textile properties. The electromechanical properties of the textile fibrous sensors confirmed their suitability for in situ structural damages detection of textile reinforced thermoplastic composites in real time.

摘要

许多用于交通运输行业的金属结构和非结构部件都可以用纺织增强复合材料来替代。过去十年,人们越来越多地研究由聚合物基体和纤维增强材料制成的复合材料。另一方面,智能纺织结构的快速发展似乎为复合材料部件的原位结构健康监测提供了一个非常有前途的解决方案。为了优化复合材料的质量和使用寿命,所有生产步骤都必须进行实时监测。嵌入在复合材料增强体中的纺织传感器与用于制造增强体的纱线具有相同的机械性能,具有致动和传感功能。本文提出了一种基于导电聚合物复合物聚(3,4-乙二氧基噻吩)-聚(苯乙烯磺酸盐)的新一代纺织纤维传感器,该复合物是通过原始的卷对卷涂层方法开发的。根据该聚合物复合物渗流阈值的初步研究,确定了纱线处理的导电涂层。渗流阈值的确定是基于导电干膜的电性能分析,以开发高灵敏度的传感器。为了确保在不改变纺织品性能的情况下,对导电聚合物进行有效且均匀的涂层,设计并制作了一种新型的纱线涂层实验室设备。纺织纤维传感器的机电性能证实了它们适用于实时检测纺织增强热塑性复合材料的原位结构损伤。

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