Giereth Robin, Frey Wolfgang, Junge Henrik, Tschierlei Stefanie, Karnahl Michael
Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.
Leibniz-Institute for Catalysis at the University of Rostock (LIKAT), Albert-Einstein-Str. 29a, 18059, Rostock, Germany.
Chemistry. 2017 Dec 11;23(69):17432-17437. doi: 10.1002/chem.201703672. Epub 2017 Nov 10.
Driven by the intention to improve classic heteroleptic copper photosensitizers two novel Cu(I) complexes applying a hetero-bidentate P^N ligand were prepared. A combined photophysical, electrochemical, and theoretical study gives insights into structure-activity relationships and revealed an increased absorptivity. Both complexes were tested for the light-driven production of H .
出于改进经典异配体铜光敏剂的目的，制备了两种应用杂双齿P^N配体的新型Cu(I)配合物。一项结合光物理、电化学和理论的研究深入探讨了构效关系，并揭示了吸收率的提高。对这两种配合物进行了光驱动产氢测试。
