El-Eskandarany M Sherif, Shaban Ehab, Aldakheel Fahad, Alkandary Abdullah, Behbehani Montaha, Al-Saidi M
Nanotechnology and Advanced Materials Program, Energy and Building Research Center, Kuwait Institute for Scientific Research, Safat, 13109, Kuwait, Kuwait.
Environment Pollution and Climate Program, Environment and Life Sciences Research Center, Kuwait Institute for Scientific Research, Safat, 13109, Kuwait, Kuwait.
Sci Rep. 2017 Oct 16;7(1):13296. doi: 10.1038/s41598-017-13483-0.
Storing hydrogen gas into cylinders under high pressure of 350 bar is not safe and still needs many intensive studies dedic ated for tank's manufacturing. Liquid hydrogen faces also severe practical difficulties due to its very low density, leading to larger fuel tanks three times larger than traditional gasoline tank. Moreover, converting hydrogen gas into liquid phase is not an economic process since it consumes high energy needed to cool down the gas temperature to -252.8 °C. One practical solution is storing hydrogen gas in metal lattice such as Mg powder and its nanocomposites in the form of MgH. There are two major issues should be solved first. One related to MgH in which its inherent poor hydrogenation/dehydrogenation kinetics and high thermal stability must be improved. Secondly, related to providing a safe tank. Here we have succeeded to prepare a new binary system of MgH/5 wt. % TiMn nanocomposite powder that show excellent hydrogenation/dehydrogenation behavior at relatively low temperature (250 °C) with long cycle-life-time (1400 h). Moreover, a simple hydrogen storage tank filled with our synthetic nanocomposite powders was designed and tested in electrical charging a battery of a cell phone device at 180 °C through a commercial fuel cell.
在350巴的高压下将氢气储存到气瓶中并不安全,仍需要进行许多深入研究以致力于气瓶的制造。液态氢由于其极低的密度也面临着严峻的实际困难,这导致其燃料箱比传统汽油箱大三倍。此外,将氢气转化为液相并非一个经济的过程,因为它需要消耗大量能量将气体温度冷却至-252.8°C。一种实际的解决方案是以MgH形式将氢气储存在金属晶格中,如镁粉及其纳米复合材料。首先有两个主要问题需要解决。一个与MgH有关,其固有的氢化/脱氢动力学较差且热稳定性较高,必须加以改善。其次,与提供一个安全的储箱有关。在这里,我们成功制备了一种新的MgH/5 wt.% TiMn纳米复合粉末二元体系,该体系在相对较低的温度(250°C)下表现出优异的氢化/脱氢行为,且循环寿命长(1400小时)。此外,设计了一个装有我们合成的纳米复合粉末的简单储氢箱,并通过商用燃料电池在180°C下对手机设备的电池进行充电测试。