• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

科威特科学研究所基于氢化镁的固体氢材料在制备、表征及应用方面的最新进展。

Recent developments in the fabrication, characterization and implementation of MgH-based solid-hydrogen materials in the Kuwait Institute for Scientific Research.

作者信息

El-Eskandarany Mohamed Sherif

机构信息

Nanotechnology and Advanced Materials Program, Energy and Building Research Center, Kuwait Institute for Scientific Research Safat 13109 Kuwait

出版信息

RSC Adv. 2019 Mar 29;9(18):9907-9930. doi: 10.1039/c9ra00287a. eCollection 2019 Mar 28.

DOI:10.1039/c9ra00287a
PMID:35520942
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9062535/
Abstract

Hydrogen energy holds tremendous promise as a new clean energy option. It is a convenient, safe, versatile fuel source that can be easily converted to the desired form of energy without releasing harmful emissions. Hydrogen storage, which spans both hydrogen production and hydrogen applications, plays a critical role in initiating a hydrogen economy. Apart from the traditional methods used for hydrogen storage, Mg metal has been considered to be the most suitable candidate for application as a safe hydrogen storage material. However, Mg still has several technical problems that must be solved before such an attractive light metal can be considered for use in real applications. This review article aims to present and discuss the most recent research activities (2010-2018) that have been undertaken at the Kuwait Institute for Scientific Research (KISR) to develop and implement new categories of MgH-based nanocomposites. Comparisons between different catalytic agents used to enhance MgH properties are presented and discussed in terms of structure, morphology, thermal stability, and kinetics.

摘要

氢能作为一种新的清洁能源选择，具有巨大的潜力。它是一种便捷、安全、用途广泛的燃料源，能够在不释放有害排放物的情况下轻松转化为所需的能源形式。涵盖制氢和氢应用的储氢，在启动氢能经济中起着关键作用。除了用于储氢的传统方法外，镁金属被认为是用作安全储氢材料的最合适候选者。然而，在这种有吸引力的轻金属能够被考虑用于实际应用之前，镁仍然存在几个必须解决的技术问题。这篇综述文章旨在介绍和讨论科威特科学研究机构（KISR）在2010年至2018年期间开展的最新研究活动，这些活动旨在开发和应用新型的基于MgH的纳米复合材料。文章还根据结构、形态、热稳定性和动力学，对用于增强MgH性能的不同催化剂进行了比较和讨论。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/504ed6d49fad/c9ra00287a-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ca0c6be882fe/c9ra00287a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/909455fbc809/c9ra00287a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/63505d10fafe/c9ra00287a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/291c6f88b2fb/c9ra00287a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/3ec9df1cc188/c9ra00287a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/c52a09f50e89/c9ra00287a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/72121d226202/c9ra00287a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/6f00d42c0654/c9ra00287a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/365dbc49e94f/c9ra00287a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/13e7a4b3cf3a/c9ra00287a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/7ba1b5cafc2a/c9ra00287a-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/a342a6908e56/c9ra00287a-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/c1746805bb90/c9ra00287a-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/313f7798abee/c9ra00287a-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/463561e77646/c9ra00287a-f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ee4b4a6392b8/c9ra00287a-f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/949cb7577144/c9ra00287a-f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ef335fb753ad/c9ra00287a-f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/cb0ed545f25d/c9ra00287a-f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/86fda9310865/c9ra00287a-f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/925ed47e10c4/c9ra00287a-f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/64957a03f5e8/c9ra00287a-f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/f1bc9260c93a/c9ra00287a-f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/d6678f9cc8a3/c9ra00287a-f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/5a21347b6742/c9ra00287a-f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/504ed6d49fad/c9ra00287a-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ca0c6be882fe/c9ra00287a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/909455fbc809/c9ra00287a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/63505d10fafe/c9ra00287a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/291c6f88b2fb/c9ra00287a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/3ec9df1cc188/c9ra00287a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/c52a09f50e89/c9ra00287a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/72121d226202/c9ra00287a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/6f00d42c0654/c9ra00287a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/365dbc49e94f/c9ra00287a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/13e7a4b3cf3a/c9ra00287a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/7ba1b5cafc2a/c9ra00287a-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/a342a6908e56/c9ra00287a-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/c1746805bb90/c9ra00287a-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/313f7798abee/c9ra00287a-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/463561e77646/c9ra00287a-f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ee4b4a6392b8/c9ra00287a-f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/949cb7577144/c9ra00287a-f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/ef335fb753ad/c9ra00287a-f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/cb0ed545f25d/c9ra00287a-f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/86fda9310865/c9ra00287a-f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/925ed47e10c4/c9ra00287a-f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/64957a03f5e8/c9ra00287a-f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/f1bc9260c93a/c9ra00287a-f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/d6678f9cc8a3/c9ra00287a-f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/5a21347b6742/c9ra00287a-f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b23/9062535/504ed6d49fad/c9ra00287a-p1.jpg

相似文献

1
Recent developments in the fabrication, characterization and implementation of MgH-based solid-hydrogen materials in the Kuwait Institute for Scientific Research.科威特科学研究所基于氢化镁的固体氢材料在制备、表征及应用方面的最新进展。
RSC Adv. 2019 Mar 29;9(18):9907-9930. doi: 10.1039/c9ra00287a. eCollection 2019 Mar 28.
2
From gangue to the fuel-cells application.从煤矸石到燃料电池应用。
Sci Rep. 2020 Nov 18;10(1):20022. doi: 10.1038/s41598-020-76503-6.
3
Transition metal (Co, Ni) nanoparticles wrapped with carbon and their superior catalytic activities for the reversible hydrogen storage of magnesium hydride.包覆有碳的过渡金属（钴、镍）纳米颗粒及其对氢化镁可逆储氢的优异催化活性。
Phys Chem Chem Phys. 2017 Feb 1;19(5):4019-4029. doi: 10.1039/c6cp07852d.
4
Synthetic nanocomposite MgH/5 wt. % TiMn powders for solid-hydrogen storage tank integrated with PEM fuel cell.用于与质子交换膜燃料电池集成的固体储氢罐的合成纳米复合MgH/5重量% TiMn粉末。
Sci Rep. 2017 Oct 16;7(1):13296. doi: 10.1038/s41598-017-13483-0.
5
Hydrogen Storage Performance of Mg/MgH and Its Improvement Measures: Research Progress and Trends.Mg/MgH的储氢性能及其改进措施：研究进展与趋势
Materials (Basel). 2023 Feb 14;16(4):1587. doi: 10.3390/ma16041587.
6
The Improvement in Hydrogen Storage Performance of MgH Enabled by Multilayer TiC.多层TiC使MgH储氢性能得到改善。
Micromachines (Basel). 2021 Sep 30;12(10):1190. doi: 10.3390/mi12101190.
7
Hydrogenation properties and kinetic study of MgH - x wt% AC nanocomposites prepared by ball milling.球磨法制备的MgH - x wt% AC纳米复合材料的氢化性能及动力学研究
Environ Sci Pollut Res Int. 2021 Jan;28(4):3872-3879. doi: 10.1007/s11356-020-08964-1. Epub 2020 May 11.
8
Solar-Driven Reversible Hydrogen Storage.太阳能驱动的可逆储氢
Adv Mater. 2023 Jan;35(2):e2206946. doi: 10.1002/adma.202206946. Epub 2022 Nov 28.
9
Superior catalytic effects of FeCo nanosheets on MgH for hydrogen storage.FeCo纳米片对用于储氢的MgH具有优异的催化作用。
Dalton Trans. 2019 Sep 7;48(33):12699-12706. doi: 10.1039/c9dt02084e. Epub 2019 Aug 6.
10
Revealing the effect of 2D carbides with different metal sites for improving hydrogen storage in MgH.揭示具有不同金属位点的二维碳化物对改善MgH储氢性能的影响。
Front Chem. 2022 Sep 21;10:1000408. doi: 10.3389/fchem.2022.1000408. eCollection 2022.

引用本文的文献

1
The Hydrogen Storage Properties and Catalytic Mechanism of the AZ31-WS Nanotube/Pd Composite.AZ31-WS纳米管/Pd复合材料的储氢性能及催化机理
Nanomaterials (Basel). 2025 May 27;15(11):802. doi: 10.3390/nano15110802.
2
Recent Development in Nanoconfined Hydrides for Energy Storage.纳米受限氢化物在储能方面的最新进展。
Int J Mol Sci. 2022 Jun 26;23(13):7111. doi: 10.3390/ijms23137111.
3
Environmentally friendly nanocrystalline magnesium hydride decorated with metallic glassy-zirconium palladium nanopowders for fuel cell applications.

本文引用的文献

1
Performance and fuel cell applications of reacted ball-milled MgH/5.3 wt% TiH nanocomposite powders.反应球磨制备的MgH₂/5.3 wt% TiH₂纳米复合粉末的性能及燃料电池应用
RSC Adv. 2018 Nov 14;8(67):38175-38185. doi: 10.1039/c8ra06570e.
2
Discovering a new MgH metastable phase.发现一种新的氢化镁亚稳相。
RSC Adv. 2018 Sep 14;8(56):32003-32008. doi: 10.1039/c8ra07068g. eCollection 2018 Sep 12.
3
Nanostructured Metal Hydrides for Hydrogen Storage.用于储氢的纳米结构金属氢化物
用于燃料电池应用的、装饰有金属玻璃态锆钯纳米粉末的环境友好型纳米晶氢化镁。
RSC Adv. 2019 Sep 6;9(48):27987-27995. doi: 10.1039/c9ra05121j. eCollection 2019 Sep 3.
4
Hydrogen storage behavior of nanocrystalline and amorphous Mg-Ni-Cu-La alloys.纳米晶和非晶态Mg-Ni-Cu-La合金的储氢行为
RSC Adv. 2020 Sep 8;10(55):33103-33111. doi: 10.1039/d0ra05417h. eCollection 2020 Sep 7.
5
Reduction and oxidation kinetics of NiWO as an oxygen carrier for hydrogen storage by a chemical looping process.作为化学链过程中储氢氧载体的NiWO的还原和氧化动力学
RSC Adv. 2021 Sep 2;11(47):29453-29465. doi: 10.1039/d1ra05077j. eCollection 2021 Sep 1.
6
Phase Transformations from Nanocrystalline to Amorphous (ZrNiAl)W (x; 0, 2, 10, 20, 35 at. %) and Subsequent Consolidation.从纳米晶到非晶（ZrNiAl）W（x；0、2、10、20、35原子百分比）的相变及随后的固结。
Nanomaterials (Basel). 2021 Nov 3;11(11):2952. doi: 10.3390/nano11112952.
7
Mechanical Milling: A Superior Nanotechnological Tool for Fabrication of Nanocrystalline and Nanocomposite Materials.机械研磨：一种用于制备纳米晶体和纳米复合材料的卓越纳米技术工具。
Nanomaterials (Basel). 2021 Sep 24;11(10):2484. doi: 10.3390/nano11102484.
8
Effect of ZrC Nanopowders on Enhancing the Hydro/Dehydrogenation Kinetics of MgH Powders.ZrC纳米粉末对增强MgH粉末加氢/脱氢动力学的影响。
Molecules. 2021 Aug 17;26(16):4962. doi: 10.3390/molecules26164962.
9
Cold Gas-Dynamic Spray for Catalyzation of Plastically Deformed Mg-Strips with Ni Powder.用于用镍粉催化塑性变形镁带的冷气体动力喷涂
Nanomaterials (Basel). 2021 Apr 29;11(5):1169. doi: 10.3390/nano11051169.
10
From gangue to the fuel-cells application.从煤矸石到燃料电池应用。
Sci Rep. 2020 Nov 18;10(1):20022. doi: 10.1038/s41598-020-76503-6.
Chem Rev. 2018 Nov 28;118(22):10775-10839. doi: 10.1021/acs.chemrev.8b00313. Epub 2018 Oct 2.
4
Synthetic nanocomposite MgH/5 wt. % TiMn powders for solid-hydrogen storage tank integrated with PEM fuel cell.用于与质子交换膜燃料电池集成的固体储氢罐的合成纳米复合MgH/5重量% TiMn粉末。
Sci Rep. 2017 Oct 16;7(1):13296. doi: 10.1038/s41598-017-13483-0.
5
Contamination Effects on Improving the Hydrogenation/Dehydrogenation Kinetics of Binary Magnesium Hydride/Titanium Carbide Systems Prepared by Reactive Ball Milling.污染对通过反应球磨制备的二元氢化镁/碳化钛体系氢化/脱氢动力学改善的影响
Materials (Basel). 2015 Oct 10;8(10):6880-6892. doi: 10.3390/ma8105350.
6
In-situ catalyzation approach for enhancing the hydrogenation/dehydrogenation kinetics of MgH powders with Ni particles.利用镍颗粒增强MgH粉末氢化/脱氢动力学的原位催化方法。
Sci Rep. 2016 Nov 16;6:37335. doi: 10.1038/srep37335.
7
Metallic glassy Zr70Ni20Pd10 powders for improving the hydrogenation/dehydrogenation behavior of MgH2.用于改善MgH2氢化/脱氢行为的金属玻璃Zr70Ni20Pd10粉末。
Sci Rep. 2016 May 25;6:26936. doi: 10.1038/srep26936.
8
Facile preparation of β-/γ-MgH₂ nanocomposites under mild conditions and pathways to rapid dehydrogenation.在温和条件下简便制备β-/γ-MgH₂纳米复合材料及快速脱氢途径。
Phys Chem Chem Phys. 2016 Apr 21;18(15):10492-8. doi: 10.1039/c5cp07762a. Epub 2016 Mar 31.
9
Effective hydrogen storage: a strategic chemistry challenge.有效储氢：一项具有战略意义的化学挑战。
Faraday Discuss. 2011;151:399-414. doi: 10.1039/c1fd00105a.
10
Pressure-induced structural transitions in MgH2.氢化镁中压力诱导的结构转变。
Phys Rev Lett. 2002 Oct 21;89(17):175506. doi: 10.1103/PhysRevLett.89.175506. Epub 2002 Oct 8.