使用金亲和力指数和氢键碱性指数预测抗衡离子效应。
Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index.
机构信息
Department of Chemistry, University of Louisville , Louisville, Kentucky 40292, United States.
Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University , Gunma 376-8515, Japan.
出版信息
Org Lett. 2017 Nov 3;19(21):5848-5851. doi: 10.1021/acs.orglett.7b02829.
PMID:29058906
Abstract
We have developed a gold affinity index and hydrogen bonding basicity index for counterions and have used these indexes to forecast their reactivity in cationic gold catalysis.
摘要
我们已经开发了一种用于反离子的金亲和力指数和氢键碱性指数，并使用这些指数来预测它们在阳离子金催化中的反应活性。
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