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含二苯基甘脲片段和苯并冠醚的分子夹与百草枯及其衍生物的络合作用。

Complexation of molecular clips containing fragments of diphenylglycoluril and benzocrown ethers with paraquat and its derivatives.

作者信息

Kikot' Leonid S, Kulygina Catherine Yu, Lyapunov Alexander Yu, Shishkina Svetlana V, Zubatyuk Roman I, Bogaschenko Tatiana Yu, Kirichenko Tatiana I

机构信息

Department of Fine Organic Synthesis, A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya doroga 86, Odesa 65080, Ukraine.

Department of X-ray Diffraction Studies and Quantum Chemistry, SSI ''Institute for Single Crystals'', National Academy of Sciences of Ukraine, Nauky Ave. 60, Kharkiv 61001, Ukraine.

出版信息

Beilstein J Org Chem. 2017 Oct 4;13:2056-2067. doi: 10.3762/bjoc.13.203. eCollection 2017.

Abstract

The complexation of molecular clips containing fragments of diphenylglycoluril and benzocrown ethers with paraquat and its derivatives has been studied both in solution and in the solid state. In this paper we studied the influence of the crown ether ring size and the nature of the substituents at the nitrogen atoms of the paraquat derivatives on the composition and stability of these complexes.

摘要

含二苯基甘脲片段和苯并冠醚的分子夹与百草枯及其衍生物的络合作用已在溶液和固态中进行了研究。在本文中,我们研究了冠醚环大小和百草枯衍生物氮原子上取代基的性质对这些络合物的组成和稳定性的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31d8/5647707/4500db0d3dc8/Beilstein_J_Org_Chem-13-2056-g002.jpg

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