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Experimental observation of hysteresis in a coherent metal-hydride phase transition.

作者信息

Huang Wen, Pã Lsson Gunnar K, Brischetto Martin, Droulias Sotirios A, Hartmann Ola, Wolff Max, Hjà Rvarsson Bjà Rgvin

机构信息

Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala, Sweden.

出版信息

J Phys Condens Matter. 2017 Dec 13;29(49):495701. doi: 10.1088/1361-648X/aa9696.

DOI:10.1088/1361-648X/aa9696
PMID:29077571
Abstract

We investigate the hysteresis obtained in the hydrogen absorption and desorption cycle for a single crystal [Formula: see text] superlattice. Below the critical temperature, a small but clear hysteresis is observed in the pressure-composition isotherms, while it is absent above. The experimental results thereby prove the relevance of macroscopic energy barriers for obtaining hysteresis in coherent structural transformations. The textured Pd layer exhibits substantially larger hysteresis effects, which can be related to an irreversible energy loss caused by defect generation in Pd.

摘要

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