A Fluorinated Cobalt(III) Porphyrin Complex for Hydroalkoxylation of Alkynes.
作者信息
Ushimaru Richiro, Nishimura Takuho, Iwatsuki Toshiki, Naka Hiroshi
机构信息
Department of Chemistry, Graduate School of Science, Nagoya University.
Research Center for Materials Science, Nagoya University.
出版信息
Chem Pharm Bull (Tokyo). 2017;65(11):1000-1003. doi: 10.1248/cpb.c17-00568.
PMID:29093285
Abstract
A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)NTf·2CHOH, where TPFPP=5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, Tf=CFSO] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.
摘要
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