Department of Materials Science and Engineering, Henry Samueli School of Engineering and Applied Science, University of California Los Angeles , Los Angeles, California 90095, United States.
Department of Electronics Science and Engineering, State Key Laboratory on Integrated Optoelectronics, Jilin University , Changchun 130012, China.
ACS Nano. 2017 Nov 28;11(11):11368-11375. doi: 10.1021/acsnano.7b05935. Epub 2017 Nov 7.
A light-emitting touch-responsive device (LETD) for instantaneous visualization of pressure mapping is reported. The LETD integrates an organometal halide perovskite polymer composite emissive layer and a flexible silver nanowire polyurethane composite transparent electrode. The composite emissive layer contains methylammonium lead bromide nanocrystals uniformly dispersed in a poly(ethylene oxide) (PEO) matrix and emits an intense green luminescence that peaks at 529 nm. The PEO matrix promotes the formation of small perovskite grains (∼20 nm) and a pinhole-free composite film with surface roughness of only 2.96 nm. The composite transparent electrode is separated from the emissive layer with a 100 μm thick spacer. When a local pressure is applied, a Schottky contact is formed instantaneously between the metal and the emissive layer, and electroluminescence is produced at voltages as low as 2.5 V and reaches 1030 cd/m at 6 V. The transparent LETD has approximately 68% transparency. It can be bent to a 6 mm radius when polyethylene terephthalate is used as the substrate. The perovskite LETD has fast response and can be pixelated to offer potential applications in robotics, motion detection, fingerprint devices, and interactive wallpapers.
一种用于即时可视化压力映射的发光触摸响应器件(LETD)被报道。该 LETD 集成了有机金属卤化物钙钛矿聚合物复合发射层和柔性银纳米线聚氨酯复合透明电极。复合发射层含有均匀分散在聚氧化乙烯(PEO)基质中的溴化甲基铵铅纳米晶,发出峰值为 529nm 的强烈绿光。PEO 基质促进了小钙钛矿晶粒(~20nm)的形成和具有仅 2.96nm 表面粗糙度的无针孔复合膜。复合透明电极通过 100μm 厚的间隔物与发射层隔开。当施加局部压力时,金属和发射层之间会立即形成肖特基接触,并且在低至 2.5V 的电压下会产生电致发光,在 6V 时达到 1030cd/m。透明 LETD 的透光率约为 68%。当使用聚对苯二甲酸乙二醇酯作为基板时,它可以弯曲到 6mm 的半径。钙钛矿 LETD 具有快速响应能力,可以进行像素化,从而为机器人技术、运动检测、指纹设备和交互式壁纸等领域提供潜在应用。