Aliabadi Azar, Büchner Bernd, Kataev Vladislav, Rüffer Tobias
Leibnitz Institute for Solid State and Materials Research, IFW Dresden, Helmholtzstrasse 20, D-01069 Dresden, Germany.
Institut für Festkörperphysik, TU Dresden, Zellescher Weg 16, D-01062 Dresden, Germany.
Beilstein J Nanotechnol. 2017 Oct 27;8:2245-2256. doi: 10.3762/bjnano.8.224. eCollection 2017.
For future molecular spintronic applications the possibility to modify and tailor the magnetic properties of transition-metal complexes is very promising. One of such possibilities is given by the countless derivatization offered by carbon chemistry. They allow for altering chemical structures and, in doing so, to tune magnetic properties of molecular spin-carrying compounds. With emphasis on the interplay of the spin density distribution of mononuclear and magnetic superexchange couplings of trinuclear bis(oxamato)-type complexes we review on efforts on such magneto-structural correlations.
对于未来的分子自旋电子学应用而言，修饰和定制过渡金属配合物的磁性这一可能性非常具有前景。碳化学提供的无数衍生化反应就是其中一种可能性。它们能够改变化学结构，进而调节分子自旋载体化合物的磁性。我们着重探讨单核自旋密度分布与三核双（草酰胺）型配合物的磁超交换耦合之间的相互作用，并综述在这种磁结构相关性方面所做的努力。
