Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.
Chem Soc Rev. 2018 Jan 2;47(1):172-194. doi: 10.1039/c7cs00529f.
Transition metal catalysts are formidable tools towards greener chemistry, allowing for low-waste, energy-efficient, and selective reactions. And transition metal-catalysed carbonylation procedures are powerful methodologies for producing carbonyl-containing compounds. The existing reviews/chapters/books are mainly focused on noble metal (Ru, Rh, Ir, Pd, Pt) catalysed carbonylation reactions. In this review, achievements on non-noble metal (Mn, Fe, Cu, Co, Ni) catalysed carbonylative transformations have been summarized and discussed.
过渡金属催化剂是实现绿色化学的有力工具,可实现低废物、节能和选择性反应。过渡金属催化的羰基化反应是一种生产含羰基化合物的有效方法。现有的综述/章节/书籍主要集中在贵金属(Ru、Rh、Ir、Pd、Pt)催化的羰基化反应上。在这篇综述中,总结和讨论了非贵金属(Mn、Fe、Cu、Co、Ni)催化的羰基化转化的成就。