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金属氧化物量子点/纳米片复合材料用于神经毒素化合物的微波辅助光催化:光腐蚀抑制、可重复使用性及抗菌活性研究

Microwave-assisted photocatalysis of neurotoxin compounds using metal oxides quantum dots/nanosheets composites: Photocorrosion inhibition, reusability and antibacterial activity studies.

作者信息

Fakhri Ali, Azad Mona, Fatolahi Leila, Tahami Shiva

机构信息

Young Researchers and Elites Club, Science and Research Branch, Islamic Azad University, Tehran, Iran.

Department of Chemical Engineering, North Tehran Branch, Islamic Azad University, Tehran, Iran.

出版信息

J Photochem Photobiol B. 2018 Jan;178:108-114. doi: 10.1016/j.jphotobiol.2017.10.038. Epub 2017 Nov 10.

Abstract

Water pollution caused by different pollutants is one of the challenging tasks for the scientific community. We have prepared and characterized a material for removal of pollutant compounds. ZnO quantum dots decorated CuO nanosheets and TiO quantum dots decorated WO nanosheets composites have been prepared using a hydrothermal method. The as synthesized catalysts were characterized by various techniques. The crystallite sizes of CuO NSs and WO NSs were to be obtained 12.5 and 13.25nm and when dopped with ZnO and TiO size reduces to 3.2 and 3.9nm, respectively. The energy band gap of the CuO NSs, WO NSs, ZnO QDs/CuO NSs and TiO QDs/WO NSs composite are calculated to be 2.01, 2.61, 1.86 and 2.32eV, respectively. The prepared catalysts are efficiently utilized for the photocatalytic degradation of two neurotoxin compounds under UV and UV coupled with microwave irradiation. The prepared catalyst composites reveal excellent photocatalytic degradation of neurotoxin compound by degrading it up to 75% under UV and UV/microwave irradiation. The photocalysis efficiency in UV/microwave system is higher than UV system. The result shows that the ZnO QDs/CuO NSs and TiO QDs/WO NSs composites have excellent photocorrosion inhibition and reusability properties. Thus, prepared samples with positive surface potential upon interaction with negative surface potential of Enterococcus faecalis and Micrococcus luteus.

摘要

不同污染物造成的水污染是科学界面临的具有挑战性的任务之一。我们制备并表征了一种用于去除污染物化合物的材料。采用水热法制备了氧化锌量子点修饰的氧化铜纳米片和二氧化钛量子点修饰的氧化钨纳米片复合材料。通过各种技术对合成的催化剂进行了表征。氧化铜纳米片和氧化钨纳米片的微晶尺寸分别为12.5和13.25nm,当掺杂氧化锌和二氧化钛时,尺寸分别减小到3.2和3.9nm。计算得出氧化铜纳米片、氧化钨纳米片、氧化锌量子点/氧化铜纳米片和二氧化钛量子点/氧化钨纳米片复合材料的能带隙分别为2.01、2.61、1.86和2.32eV。制备的催化剂在紫外光以及紫外光与微波辐照耦合条件下有效地用于两种神经毒素化合物的光催化降解。制备的催化剂复合材料在紫外光和紫外光/微波辐照下对神经毒素化合物具有优异的光催化降解性能,降解率高达75%。紫外光/微波系统中的光催化效率高于紫外光系统。结果表明,氧化锌量子点/氧化铜纳米片和二氧化钛量子点/氧化钨纳米片复合材料具有优异的光腐蚀抑制和可重复使用性能。因此,制备的样品在与粪肠球菌和藤黄微球菌的负表面电位相互作用时具有正表面电位。

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