超声辐射对 3D 纳米锌(II)超分子配位聚合物形态性能的影响。
Ultrasound irradiation effect on morphological properties of a 3D nano zinc(II) supramolecular coordination polymer.
机构信息
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, No. 21 Bohai Road, Caofeidian New-city, Tangshan, Hebei 063210, PR China.
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, No. 21 Bohai Road, Caofeidian New-city, Tangshan, Hebei 063210, PR China.
出版信息
Ultrason Sonochem. 2018 Mar;41:67-74. doi: 10.1016/j.ultsonch.2017.09.024. Epub 2017 Sep 18.
Nano-structures of [Zn(L)(atpt)] (1) (L=1,2-bis(2-methylbenzimidazol-1-ylmethyl)benzene and Hatpt=2-aminoterephthalic acid) were obtained by hydrothermal and sonochemical approaches, characterized by scanning electron microscopy (SEM), IR, powder X-ray diffraction (PXRD), and elemental analysis. CP 1 features a 2D (4,4) network with the point symbol {4.6}, the 3D supramolecular architecture in CP 1 is controlled through π⋯π stacking interactions. The influence of various concentrations of initial reagents, power of ultrasound irradiation, and ultrasound time on the morphology and size of nano-structured CP 1 were studied in detail. In addition, the luminescence and photocatalytic properties of the nanoparticles of CP 1 for the degradation of methyl blue (MB) have also been investigated.
通过水热和超声化学方法得到了[Zn(L)(atpt)]（1）（L=1,2-双（2-甲基苯并咪唑-1-基甲基）苯，Hatpt=2-氨基对苯二甲酸）的纳米结构，通过扫描电子显微镜（SEM）、红外（IR）、粉末 X 射线衍射（PXRD）和元素分析进行了表征。CP1 具有二维（4,4）网络，点符号为{4.6}，CP1 中的 3D 超分子结构通过π⋯π堆积相互作用控制。详细研究了初始试剂浓度、超声辐射功率和超声时间对 CP1 纳米结构形貌和尺寸的影响。此外，还研究了 CP1 纳米粒子对亚甲基蓝（MB）降解的发光和光催化性能。
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