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扭肚藤茎皮中的木脂素和裂环烯醚萜苷

Lignans and secoiridoid glycosides from the stem barks of Jasminum tortuosum.

作者信息

Tomassini Lamberto, Ventrone Antonio, Frezza Claudio, Serafini Ilaria, Bianco Armandodoriano, Cometa Maria Francesca

机构信息

a Dipartimento di Biologia ambientale , Università di Roma 'La Sapienza' , Rome , Italy.

b Dipartimento di Chimica , Università di Roma 'La Sapienza' , Rome , Italy.

出版信息

Nat Prod Res. 2018 Aug;32(15):1853-1857. doi: 10.1080/14786419.2017.1404597. Epub 2017 Nov 15.

Abstract

This paper reports on the first phytochemical analysis ever performed on Jasminum tortuosum Willd. This analysis, mainly carried out by means of column chromatography separation, NMR spectroscopy and mass spectrometry, led to the isolation and the identification of four compounds, namely the lignans ginkgool (1) and olivil-4'-O-β-glucopyranoside (2) and the secoiridoids oleoside dimethyl ester (3) and oleoside 11-methyl ester (4). The presence of these compounds is significant from a chemotaxonomic point of view, confirming the correct botanical classification of the species and, from a phytochemical standpoint, may suggest its possible use in the ethno-medicinal field.

摘要

本文报道了对扭肚藤(Jasminum tortuosum Willd.)首次进行的植物化学分析。该分析主要通过柱色谱分离、核磁共振光谱和质谱法进行,结果分离并鉴定出四种化合物,即木脂素银杏醇(1)和橄榄脂素-4'-O-β-吡喃葡萄糖苷(2)以及裂环环烯醚萜类橄榄苦苷二甲基酯(3)和橄榄苦苷11-甲酯(4)。从化学分类学角度来看,这些化合物的存在意义重大,证实了该物种正确的植物学分类,并且从植物化学角度而言,可能暗示了其在民族医药领域的潜在用途。

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