Uetani Kojiro, Hatori Kimihito
Department of Chemistry, College of Science, Rikkyo University, Tokyo, Japan.
Hudson Laboratory, Bethel Co., Ltd., Ibaraki, Japan.
Sci Technol Adv Mater. 2017 Nov 3;18(1):877-892. doi: 10.1080/14686996.2017.1390692. eCollection 2017.
In this review, we summarize the recent progress in thermal conductivity analysis of nanocellulose materials called cellulose nanopapers, and compare them with polymeric materials, including neat polymers, composites, and traditional paper. It is important to individually measure the in-plane and through-plane heat-conducting properties of two-dimensional planar materials, so steady-state and non-equilibrium methods, in particular the laser spot periodic heating radiation thermometry method, are reviewed. The structural dependency of cellulose nanopaper on thermal conduction is described in terms of the crystallite size effect, fibre orientation, and interfacial thermal resistance between fibres and small pores. The novel applications of cellulose as thermally conductive transparent materials and thermal-guiding materials are also discussed.
在本综述中,我们总结了被称为纤维素纳米纸的纳米纤维素材料热导率分析的最新进展,并将它们与包括纯聚合物、复合材料和传统纸张在内的聚合物材料进行比较。单独测量二维平面材料的面内和面外导热性能很重要,因此对稳态和非平衡方法,特别是激光光斑周期加热辐射测温法进行了综述。从微晶尺寸效应、纤维取向以及纤维与小孔之间的界面热阻方面描述了纤维素纳米纸对热传导的结构依赖性。还讨论了纤维素作为导热透明材料和热导材料的新应用。