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掺入滑润剂的多孔表面中光固化聚合物网络的抗冰性能:提高 SLIPS 耐久性。

Icephobic Behavior of UV-Cured Polymer Networks Incorporated into Slippery Lubricant-Infused Porous Surfaces: Improving SLIPS Durability.

机构信息

Department of Chemistry, Western University , 1151 Richmond Street, London, Ontario N6A 3K7, Canada.

Department of Chemical Engineering, McGill University , 3610 University Street, Montréal, Québec H3A 0C5, Canada.

出版信息

ACS Appl Mater Interfaces. 2018 Jan 24;10(3):2890-2896. doi: 10.1021/acsami.7b14433. Epub 2018 Jan 8.

Abstract

Ice accretion causes damage on power generation infrastructure, leading to mechanical failure. Icephobic materials are being researched so that ice buildup on these surfaces will be shed before the weight of the ice causes catastrophic damage. Lubricated materials have imposed the lowest-recorded forces of ice adhesion, and therefore lubricated materials are considered the state-of-the-art in this area. Slippery lubricant-infused porous surfaces (SLIPS) are one type of such materials. SLIPS are initially very effective at repelling ice, but the trapped fluid layer that affords their icephobic properties is easily depleted by repeated icing/deicing cycles, even after one deicing event. UV-cured siloxane resins were infused into SLIPS to observe effects on icephobicity and durability. These UV-cured polymer networks enhanced both the icephobicity and longevity of the SLIPS; values of ice adhesion below 10 kPa were recorded, and appreciable icephobicity was maintained up to 10 icing/deicing cycles.

摘要

覆冰会导致发电基础设施损坏,从而导致机械故障。目前正在研究具有抗冰性能的材料,以便在冰层重量导致灾难性损坏之前将其从这些表面脱落。润滑材料施加的冰附着力最低,因此润滑材料被认为是该领域的最新技术。滑润剂注入多孔表面(SLIPS)就是此类材料之一。SLIPS 最初在排斥冰方面非常有效,但是赋予其抗冰性能的被困流体层很容易在反复的结冰/除冰循环中耗尽,即使在一次除冰事件之后也是如此。将紫外光固化硅氧烷树脂注入 SLIPS 中,以观察其对疏冰性和耐久性的影响。这些紫外光固化聚合物网络增强了 SLIPS 的疏冰性和耐久性;记录到的冰附着力值低于 10 kPa,并且在多达 10 次结冰/除冰循环中保持了可观的疏冰性。

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