Institut für Anorganische Chemie and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg , Am Hubland, 97074 Würzburg, Germany.
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University , SE-10691 Stockholm, Sweden.
Org Lett. 2017 Dec 15;19(24):6590-6593. doi: 10.1021/acs.orglett.7b03296. Epub 2017 Nov 30.
This communication describes an efficient palladium pincer complex-catalyzed allylic C-H borylation of alkenes. The transformation exhibits high regio- and stereoselectivity with a variety of linear alkenes. A synthetically useful feature of this allylic C-H borylation method is that all allyl-Bpin products can be isolated in usually high yields. Preliminary mechanistic studies indicate that this C-H borylation reaction proceeds via Pd(IV) pincer complex intermediates.
本文描述了一种高效的钯钳形配合物催化的烯烃烯丙位 C-H 硼化反应。该转化具有高度的区域和立体选择性，适用于多种线性烯烃。这种烯丙位 C-H 硼化方法的一个合成有用的特点是，所有的烯丙基-Bpin 产物通常都可以以高收率分离得到。初步的机理研究表明，该 C-H 硼化反应通过 Pd(IV) 钳形配合物中间体进行。
