一种双亲性膦/氢键供体配体及其在金介导的炔丙酰胺环化反应中的应用。
An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides.
作者信息
Sen Srobona, Gabbaï François P
机构信息
Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.
出版信息
Chem Commun (Camb). 2017 Dec 14;53(100):13356-13358. doi: 10.1039/c7cc06065c.
PMID:29199294
Abstract
We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(i) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.
摘要
我们描述了一种具有三氟乙酰胺官能团的双亲性膦/氢键供体配体的合成、其与氯化金（I）的配位以及其作为炔丙酰胺环化的自活化催化剂的应用。
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