使用Grubbs型催化剂与N-戊并四烯基、N-烷基-N-杂环卡宾配体进行交替开环易位聚合反应。
Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N-pentiptycenyl, N-alkyl-NHC ligands.
作者信息
Vasiuta Roman, Stockert Alexander, Plenio Herbert
机构信息
Organometallic Chemistry, Alarich-Weiss-Str. 12, 64287 Darmstadt, Germany.
出版信息
Chem Commun (Camb). 2018 Feb 13;54(14):1706-1709. doi: 10.1039/c7cc08476e.
PMID:29242871
Abstract
A Grubbs-Hoveyda type catalyst with a N-pentiptycenyl, N-cyclohexyl-NHC ligand provides poly(nbe-alt-coe) with an excellent degree of alternation while lacking significant activity in the homopolymerization of cyclooctene.
摘要
一种带有N-戊并四苯基金属卡宾配体的Grubbs-Hoveyda型催化剂，在环辛烯均聚反应中活性不高，但能使聚（降冰片烯-alt-环辛烯）具有优异的交替度。
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