基于卟啉的晶态且具有永久孔隙率的金属四膦酸盐。
Crystalline and permanently porous porphyrin-based metal tetraphosphonates.
作者信息
Rhauderwiek Timo, Wolkersdörfer Konrad, Øien-Ødegaard Sigurd, Lillerud Karl-Petter, Wark Michael, Stock Norbert
机构信息
Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth Straße 2, D-24118 Kiel, Germany.
出版信息
Chem Commun (Camb). 2018 Jan 4;54(4):389-392. doi: 10.1039/c7cc07766a.
PMID:29243766
Abstract
The new porphyrin-based tetraphosphonic acid (Ni-HTPPP) was employed in the synthesis of four isostructural MOFs of composition [M(Ni-HTPPP)(HO)], denoted CAU-29 (M = Mn, Co, Ni, Cd). Ni-CAU-29 was thoroughly characterized regarding its thermal and chemical stability as well as for proton conductivity.
摘要
新型卟啉基四膦酸（Ni-HTPPP）被用于合成四种组成结构相同的金属有机框架材料[M(Ni-HTPPP)(HO)]，分别命名为CAU-29（M = Mn、Co、Ni、Cd）。对Ni-CAU-29的热稳定性、化学稳定性以及质子传导性进行了全面表征。
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