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高效磁性鸡骨生物炭去除废水中的四环素和荧光染料:两阶段吸附剂分析。

Highly efficient magnetic chicken bone biochar for removal of tetracycline and fluorescent dye from wastewater: Two-stage adsorber analysis.

机构信息

Cyprus Science University, Faculty of Engineering, Kyrenia, TRNC via Mersin 10, Turkey.

Polymeric Materials Research Laboratory, Chemistry Department, Eastern Mediterranean University, Gazimagusa, TRNC via Mersin 10, Turkey.

出版信息

J Environ Manage. 2018 Mar 1;209:9-16. doi: 10.1016/j.jenvman.2017.12.030. Epub 2017 Dec 20.

Abstract

Magnetic chicken bone biochar (MCB) was fabricated and characterised. The specific surface area, magnetisation value and pH of the MCB were found to be 328 m g, 64.7 emu/g and 8.3 respectively. The adsorptive performance of MCB for rhodamine B dye (RB) and tetracycline (TC) removal in a single and two-stage stirred adsorber (TSA) was evaluated. The TSA reduced the pressure drops, mass transfer resistances, and fouling of the adsorbent. 63.0 g MCB is required to remove 75% of RB and TC in a single-stage system within 12 h. However, the optimised TSA confirmed that 33.2 g of MCB is needed to achieve 96% removal of TC and 22.2 g for RB within 180 min of 100 mgL effluent solutions. The sorption was suitably described by the Freundlich mechanism. Based on the comparative performance, the MCB is considered a viable efficient and magnetically separable alternative adsorbent.

摘要

磁性鸡骨生物炭 (MCB) 被制备和表征。发现 MCB 的比表面积、磁化值和 pH 值分别为 328 m g、64.7 emu/g 和 8.3。评估了 MCB 在单级和两级搅拌吸附器 (TSA) 中对罗丹明 B 染料 (RB) 和四环素 (TC) 去除的吸附性能。TSA 降低了压力降、传质阻力和吸附剂的污垢。在单级系统中,需要 63.0 g MCB 在 12 小时内去除 75%的 RB 和 TC。然而,优化后的 TSA 证实,在 100 mgL 流出液中,需要 33.2 g 的 MCB 才能实现 96%的 TC 去除率,需要 22.2 g 的 MCB 才能实现 22.2 g 的 RB 去除率。吸附过程可以用 Freundlich 机制来描述。基于比较性能,MCB 被认为是一种可行的高效且可磁分离的替代吸附剂。

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