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微氧条件下新型微电解-生物反应器(MEBR)集成工艺强化煤气化废水中酚类化合物的降解。

Enhanced degradation of phenolic compounds in coal gasification wastewater by a novel integration of micro-electrolysis with biological reactor (MEBR) under the micro-oxygen condition.

机构信息

State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, 73 Huanghe Road, Nangang District, Harbin 150090, China.

School of Engineering, South China Agricultural University, Guangzhou 510642, China.

出版信息

Bioresour Technol. 2018 Mar;251:303-310. doi: 10.1016/j.biortech.2017.12.042. Epub 2017 Dec 15.

Abstract

The aim of this work was to study an integration of micro-electrolysis with biological reactor (MEBR) for strengthening removal of phenolic compounds in coal gasification wastewater (CGW). The results indicated MEBR achieved high efficiencies in removal of COD and phenolic compounds as well as improvement of biodegradability of CGW under the micro-oxygen condition. The integrated MEBR process was more favorable to improvement of the structural stability of activated sludge and biodiversity of specific functional microbial communities. Especially, Shewanella and Pseudomonas were enriched to accelerate the extracellular electron transfer, finally facilitating the degradation of phenolic compounds. Moreover, MEBR process effectively relieved passivation of Fe-C filler surface and prolonged lifespan of Fe-C filler. Accordingly, the synergetic effect between iron-carbon micro-electrolysis (ICME) and biological action played a significant role in performance of the integrated process. Therefore, the integrated MEBR was a promising practical process for enhancing CGW treatment.

摘要

本工作旨在研究微电解与生物反应器(MEBR)集成工艺强化煤气化废水(CGW)中酚类化合物去除的效果。结果表明,在微氧条件下,MEBR 对 COD 和酚类化合物的去除效率以及 CGW 可生化性的提高均具有较高的效能。与传统的生物处理工艺相比,集成 MEBR 工艺更有利于提高活性污泥的结构稳定性和特定功能微生物群落的生物多样性。特别地,希瓦氏菌属(Shewanella)和假单胞菌属(Pseudomonas)被富集以加速胞外电子转移,最终促进酚类化合物的降解。此外,MEBR 工艺有效缓解了铁碳填料表面的钝化,延长了铁碳填料的使用寿命。因此,铁碳微电解(ICME)和生物作用之间的协同效应对集成工艺的性能起着重要作用。因此,集成 MEBR 是一种很有前途的实用工艺,可用于强化 CGW 的处理。

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