一种碳硼烷内/外双负离子的晶体结构及其在超分子框架双齿配体合成中的应用。
Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks.
作者信息
Zhang Kang, Shen Yunjun, Liu Jiyong, Spingler Bernhard, Duttwyler Simon
机构信息
Department of Chemistry, Zhejiang University, Zheda Road 38, 310027, Hangzhou, P. R. China.
出版信息
Chem Commun (Camb). 2018 Feb 13;54(14):1698-1701. doi: 10.1039/c7cc07724f.
PMID:29299565
Abstract
The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CBH] is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C-[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.
摘要
报道了去质子化的单碳-闭式-十二硼酸盐[12-CN-CBH]的晶体结构。这种二价阴离子具有离域的内笼负电荷和外簇C-[Li]部分，用于合成具有形成新型超分子框架潜力的双齿配体。
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