基于多吡啶配体的堆积相互作用诱导的主客体化学和博罗梅安环。
Stacking-interaction-induced host-guest chemistry and Borromean rings based on a polypyridyl ligand.
作者信息
Zhang Hai-Ning, Gao Wen-Xi, Deng Yu-Xin, Lin Yue-Jian, Jin Guo-Xin
机构信息
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China.
出版信息
Chem Commun (Camb). 2018 Feb 8;54(13):1559-1562. doi: 10.1039/c7cc09448e.
Template-free molecular Borromean rings (BRs) and open-ended molecular capsules were realized by strategic selection of the polypyridyl ligand tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j] phenazine (TPPHZ) with a large surface area and specific geometry. The topology of these intricate architectures was constructed via precisely controlled stacking interactions, as evidenced from single-crystal X-ray analysis.
通过策略性地选择具有大表面积和特定几何形状的多吡啶配体四吡啶并[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]菲咯嗪（TPPHZ），实现了无模板分子博罗梅安环（BRs）和开口端分子胶囊。这些复杂结构的拓扑结构是通过精确控制的堆积相互作用构建的，单晶X射线分析证明了这一点。
Zotero 插件