Department of Chemical and Materials Engineering, University of Alberta, 9211-116th Street, Edmonton, AB T6G 1H9, Canada.
Molecules. 2018 Jan 6;23(1):115. doi: 10.3390/molecules23010115.
The use of zeolite catalysts for the refining of products from methanol synthesis and Fisher-Tropsch synthesis was reviewed. The focus was on fuels refining processes and differences in the application to indirect liquefaction products was compared to petroleum, which is often a case of managing different molecules. Processes covered were skeletal isomerisation of -butenes, hydroisomerisation of -butane, aliphatic alkylation, alkene oligomerisation, methanol to hydrocarbons, ethanol and heavier alcohols to hydrocarbons, carbonyls to hydrocarbons, etherification of alkenes with alcohols, light naphtha hydroisomerisation, catalytic naphtha reforming, hydroisomerisation of distillate, hydrocracking and fluid catalytic cracking. The zeolite types that are already industrially used were pointed out, as well as zeolite types that have future promise for specific conversion processes.
综述了沸石催化剂在甲醇合成和费托合成产品精制中的应用。重点介绍了燃料精制过程,并比较了间接液化产品与石油在应用上的差异,因为石油通常需要处理不同的分子。涵盖的过程包括 - 丁烯的骨架异构化、- 丁烷的加氢异构化、脂肪族烷基化、烯烃齐聚、甲醇制烃、乙醇和重醇制烃、羰基制烃、烯烃与醇的醚化、轻石脑油加氢异构化、催化重整、馏分加氢异构化、加氢裂化和流化催化裂化。指出了已经工业化使用的沸石类型,以及对特定转化过程有未来应用前景的沸石类型。