Alvarez M Angeles, García M Esther, García-Vivó Daniel, Huergo Estefanía, Ruiz Miguel A
Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo , E-33071 Oviedo, Spain.
Inorg Chem. 2018 Feb 5;57(3):912-915. doi: 10.1021/acs.inorgchem.7b02879. Epub 2018 Jan 10.
The title compound was prepared upon irradiation of acetonitrile solutions of the readily available hexacarbonyl [MoReCp(μ-H)(μ-PCy)(CO)]. The acetonitrile ligand in this compound could be replaced easily by donor molecules or displaced upon two-electron reduction. In most cases, the substitution step was followed by additional processes such as insertion into the M-H bonds, E-H bond cleavage, H elimination, and other transformations.
通过照射易于获得的六羰基[MoReCp(μ-H)(μ-PCy)(CO)]的乙腈溶液制备了标题化合物。该化合物中的乙腈配体可容易地被供体分子取代，或在双电子还原时被置换。在大多数情况下，取代步骤之后会伴随其他过程，如插入M-H键、E-H键裂解、氢消除及其他转化反应。
