Liu Fu-Ling, Li Dong, Su Li-Jie, Tao Jun
State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China.
Dalton Trans. 2018 Jan 30;47(5):1407-1411. doi: 10.1039/c7dt04205a.
A novel bent ligand-pillared three-dimensional Hofmann-type metal-organic framework, [Fe(Hbpt)Pt(CN)]·1/2Hbpt·1/2CHOH·5/2HO [1, Hbpt = 4,4'-(1H-1,2,4-triazole-3,5-diyl) dipyridine], was synthesized and crystallographically and magnetically characterized, which showed incomplete three-step spin-crossover behavior with a reversible three equal-step sequence of HS ↔ HSLS ↔ HSLS ↔ HSLS.
合成了一种新型弯曲配体支撑的三维霍夫曼型金属有机框架[Fe(Hbpt)Pt(CN)]·1/2Hbpt·1/2CHOH·5/2HO [1，Hbpt = 4,4'-(1H-1,2,4-三唑-3,5-二基)二吡啶]，并对其进行了晶体学和磁性表征，该框架表现出不完全的三步自旋交叉行为，具有HS↔HSLS↔HSLS↔HSLS的可逆三相等步序列。
