Hirasawa T, Mori R, Hirano S, Hirabayashi S, Harashima I
Shika Rikogaku Zasshi. 1979 Jul;20(51):188-93.
Linear coefficients of thermal expansion (beta) of twelve restorative composite resins, one Bis-GMA based resin and one self-curing acrylic resin were determined in the temperature range of 4 to 60 degrees C under the dry and the wet conditions on a thermomechanical analyzer. The results were as follows. 1) The thermal expansion curves obtained were nonlinear, and the transition appeared at about 40 degrees C. 2) beta reduced with the elapse of stored time and the number of times of measuring run. It appears that these phenomena were attributable to decrease of monomer remained in each case. 3) beta under the wet condition was larger than one under the dry condition, when specimens were stored for 20 days in each condition at 37 degrees C. Values of beta for composites ranged from 16.1 to 35.3 x 10(-6)/degrees C under the dry condition and from 18.1 to 55.4 x 10(-6)/degrees C under the wet condition. 4) beta of composites varied with filler content and kinds of filler and resin used. Value of beta reduced with increase of filler content, and was lower for Bis-GMA based composite resin than for MMA based composite resin.
在热机械分析仪上,于4至60摄氏度的温度范围内,在干燥和潮湿条件下测定了12种复合树脂修复材料、1种双酚A缩水甘油醚(Bis-GMA)基树脂和1种自凝丙烯酸树脂的线性热膨胀系数(β)。结果如下:1)所获得的热膨胀曲线呈非线性,转变温度约为40摄氏度。2)β随储存时间的延长和测量次数的增加而降低。这些现象似乎归因于每种情况下残留单体的减少。3)当试样在37摄氏度下分别在每种条件下储存20天时,潮湿条件下的β大于干燥条件下的β。复合材料在干燥条件下的β值范围为16.1至35.3×10⁻⁶/摄氏度,在潮湿条件下为18.1至55.4×10⁻⁶/摄氏度。4)复合材料的β随填料含量以及所用填料和树脂的种类而变化。β值随填料含量的增加而降低,双酚A缩水甘油醚(Bis-GMA)基复合树脂的β值低于甲基丙烯酸甲酯(MMA)基复合树脂。