Textile Research Division, National Research Centre, Scopus afflitiation ID 60014618, (El-Behouth St.), Dokki, Giza, Egypt.
Chemistry Department, Faculty of Science, Cairo University, Egypt.
Int J Biol Macromol. 2018 May;111:526-533. doi: 10.1016/j.ijbiomac.2018.01.013. Epub 2018 Jan 11.
This study demonstrated that antibacterial cellulosic textiles can be fabricated in eco-friendly manner by grafting of monochlorotriazinyl β-cyclodextin (MCT-βCD) onto knitted and woven cotton fabrics followed by post-loading of any of the green active ingredients namely Rosemary oil, Lavender oil, Clove oil, Cinnamon oil, Aloe vera gel, Vanillin, Ag-ions, Natural Yellow 7 and Natural Red 25 dyes into the hydrophobic cavities of grafted β-CD moieties. Some of the grafted, post-loaded fabric samples were characterized by FTIR, SEM, and EDS analysis. The enhancement in the imparted antibacterial functionality as well as durability to wash are governed by type of cellulosic substrate, kind, chemistry, antibacterial activity as well as extent of inclusion and subsequent release of the hosted bioactive agent. The obtained results revealed that the antibacterial efficacy follows the deceasing orders: i) knitted fabric > woven fabric and ii) Ag-ions > Lavender oil > Natural Yellow 7 > Aloe vera > Cinnamon oil > Natural Red 25 > Vanillin > Clove oil > Rosemary oil-loaded fabric sample, keeping other parameters constant.
本研究通过将单氯代三嗪基β-环糊精(MCT-βCD)接枝到针织和机织棉织物上,并随后将任何绿色活性成分(即迷迭香油、薰衣草油、丁香油、肉桂油、芦荟凝胶、香草醛、Ag-离子、天然黄 7 和天然红 25 染料)载入接枝β-CD 部分的疏水性空腔中,以环保的方式制造出抗菌纤维素纺织品。一些接枝、后加载的织物样品通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和能谱分析(EDS)进行了表征。赋予的抗菌功能的增强以及耐洗性取决于纤维素基质的类型、种类、化学性质、抗菌活性以及宿主生物活性剂的包含和随后的释放程度。所得结果表明,抗菌功效遵循以下递减顺序:i)针织织物>机织织物和 ii)Ag-离子>薰衣草油>天然黄 7>芦荟>肉桂油>天然红 25>香草醛>丁香油>迷迭香油负载织物样品,其他参数保持不变。