Pan Dongjiang, Zhang Nong, Zhang Chenghao, Qian Deyu, Han Changliang, Yang Sen
Key Laboratory of Deep Coal Resource Mining, School of Mines, China University of Mining and Technology, Xuzhou 221116, China.
Department of Energy and Mineral Engineering, G3 Center and Energy Institute, Pennsylvania State University, PA 16802, USA.
Nanomaterials (Basel). 2018 Jan 16;8(1):46. doi: 10.3390/nano8010046.
The longevity of grouting has a significant effect on the safe and sustainable operation of many engineering projects. A 500-day experiment was carried out to study the long-term mechanical behavior of nano silica sol grouting. The nano silica sol was activated with different proportions of a NaCl catalyst and cured under fluctuating temperature and humidity conditions. The mechanical parameters of the grout samples were tested using an electrohydraulic uniaxial compression tester and an improved Vicat instrument. Scanning electron microscope, X-ray diffraction, and ultrasonic velocity tests were carried out to analyze the strength change micro-mechanism. Tests showed that as the catalyst dosage in the grout mix is decreased, the curves on the graphs showing changes in the weight and geometric parameters of the samples over time could be divided into three stages, a shrinkage stage, a stable stage, and a second shrinkage stage. The catalyst improved the stability of the samples and reduced moisture loss. Temperature rise was also a driving force for moisture loss. Uniaxial compressive stress-strain curves for all of the samples were elastoplastic. The curves for uniaxial compression strength and secant modulus plotted against time could be divided into three stages. Sample brittleness increased with time and the brittleness index increased with higher catalyst dosages in the latter part of the curing time. Plastic strength-time curves exhibit allometric scaling. Curing conditions mainly affect the compactness, and then affect the strength.
灌浆的耐久性对许多工程项目的安全与可持续运行有着重大影响。开展了一项为期500天的试验,以研究纳米硅溶胶灌浆的长期力学行为。纳米硅溶胶用不同比例的NaCl催化剂进行活化,并在温度和湿度波动的条件下养护。使用电液单轴压缩试验机和改进的维卡仪对灌浆样品的力学参数进行测试。进行扫描电子显微镜、X射线衍射和超声波速度测试,以分析强度变化的微观机制。试验表明,随着灌浆混合料中催化剂用量的减少,样品重量和几何参数随时间变化的曲线可分为三个阶段,即收缩阶段、稳定阶段和二次收缩阶段。催化剂提高了样品的稳定性并减少了水分损失。温度升高也是水分损失的一个驱动力。所有样品的单轴压缩应力-应变曲线均为弹塑性。单轴抗压强度和割线模量随时间变化的曲线可分为三个阶段。样品的脆性随时间增加,在养护后期,脆性指数随催化剂用量的增加而增加。塑性强度-时间曲线呈现异速生长标度。养护条件主要影响密实度,进而影响强度。