Poß Marieke, Gröger Henriette, Feldmann Claus
Karlsruhe Institute of Technology (KIT), Institut für Anorganische Chemie, Engesserstraße 15, D-76131 Karlsruhe, Germany.
Chem Commun (Camb). 2018 Jan 31;54(10):1245-1248. doi: 10.1039/c7cc08115d.
The inorganic-organic hybrid nanoparticles Gd[AlPCS] and La[TPPS] ([AlPCS]: aluminium(iii) chlorido phthalocyanine tetrasulfonate; [TPPS]: tetraphenylporphine sulfonate) are shown for the first time. Both were obtained via aqueous synthesis and contain extremely high contents of [AlPCS] (81 wt%) and [TPPS] (83 wt%). They show efficient singlet oxygen (O) production upon daylight and red-light irradiation. Photocatalysis is evidenced via dye degradation as a proof-of-the-concept and proceeds with daylight and even red-light illumination.
首次展示了无机-有机杂化纳米颗粒Gd[AlPCS]和La[TPPS]（[AlPCS]：四磺酸铝酞菁氯；[TPPS]：四苯基卟啉磺酸盐）。两者均通过水相合成获得，且含有极高含量的[AlPCS]（81 wt%）和[TPPS]（83 wt%）。它们在日光和红光照射下能高效产生单线态氧（O）。通过染料降解作为概念验证证明了光催化作用，并且在日光甚至红光照射下都能进行。
