Electric-field-induced stretching of surface-tethered polyelectrolytes in a microchannel.

We study the stretching of a surface-tethered polyelectrolyte confined between parallel surfaces under the application of a dc electric field. We explore the influence of the electric-field strength, the length of the polyelectrolyte, and the degree of confinement on the conformation of the polyelectrolyte by single-molecule experiments and coarse-grained coupled lattice-Boltzmann molecular-dynamics simulations. The fractional extension of the polyelectrolyte is found to be a universal function of the product of the applied electric field and the molecular contour length, which is explained by simple scaling arguments. The degree of confinement does not have any significant influence on the stretching. We also confirm that an electrohydrodynamic equivalence principle relating the stretching in an electric field to that in a flow field is applicable.