Department of Chemical Sciences, University of Padova, via Marzolo 1, I-35131, Padova, Italy.
Phys Rev E. 2017 Dec;96(6-1):062113. doi: 10.1103/PhysRevE.96.062113. Epub 2017 Dec 11.
This work deals with thermostated fluctuating systems subjected to driven transformations of the internal energetics. The main focus is on generally multidimensional systems with continuous configurational degrees of freedom over which overdamped Markovian fluctuations take place (diffusive regime of the motion). Mutual bounds are established between the average energy dissipation, the deviation between nonequilibrium probability density and underlying equilibrium distribution due to the system's lag, and the statistical properties of the components of the directed flow induced by the transformation itself. The directed flow is here expressed in terms of time-dependent "drift velocity" associated with the probability current in a advection-like formulation of the nonstationary Fokker-Planck equation. Consideration of the drift makes that the bounds achieved here extend the inequality derived by Vaikuntanathan and Jarzynski [Europhys. Lett. 87, 60005 (2009)EULEEJ0295-507510.1209/0295-5075/87/60005] involving only dissipation and lag. The key relations are then specified for the so-called stochastic pumps, i.e., systems that reach a periodic steady state in response of cyclic transformations and that are prototypes of nonautonomous dissipative converters of input energy into directed motion; a one-dimensional case model is adopted to illustrate the main features. Complementary results concerning bounds between the evolution rates of dissipation and lag, valid for both overdamped and underdamped dynamics, are also presented.
本文研究了受到内部能量驱动转换影响的恒温涨落系统。主要关注的是具有连续构型自由度的一般多维系统,在这些系统中,存在过度阻尼的马尔可夫涨落(扩散运动状态)。建立了平均能量耗散、由于系统滞后引起的非平衡概率密度与基础平衡分布之间的偏差,以及由转换本身引起的有向流的分量的统计特性之间的相互界限。有向流在此表示为与非定常福克-普朗克方程的平流形式中的概率流相关联的时变“漂移速度”。考虑到漂移,这里获得的界限扩展了 Vaikuntanathan 和 Jarzynski 推导的仅涉及耗散和滞后的不等式[Europhys. Lett. 87, 60005 (2009)EULEEJ0295-507510.1209/0295-5075/87/60005]。然后,为所谓的随机泵(即对周期性转换做出响应并达到周期性稳态的系统,是输入能量到有向运动的非自治耗散转换器的原型)指定了关键关系;采用一维情况模型来说明主要特征。还提出了适用于过度阻尼和欠阻尼动力学的关于耗散和滞后的演化速率之间界限的补充结果。