Petrov Danil A, Skokov Pavel K, Zakhlevnykh Alexander N
Physics of Phase Transitions Department, Perm State University, Bukireva St. 15, 614990 Perm, Russia.
Beilstein J Nanotechnol. 2017 Dec 29;8:2807-2817. doi: 10.3762/bjnano.8.280. eCollection 2017.
We propose a continuum theory of orientational phase transitions induced by an external magnetic field in a suspension of carbon nanotubes in a nematic liquid crystal. It is shown that in a magnetic field a non-uniform and two different uniform phases are possible in the suspension. The uniform phases of the suspension differ by the type of orientational coupling of nanotubes with the liquid crystal matrix (the planar type when the nanotubes are oriented along the matrix director, and the homeotropic type when the nanotubes are perpendicular to the director). The possibility of a redistribution of the nanotube concentration (segregation effect) is shown. The fields of orientational transitions between uniform and non-uniform phases of the suspension are found analytically. It is shown that, when the nanotubes are weakly coupled to the matrix, the magnetic field induces reentrant transitions (uniform planar phase-non-uniform phase-uniform homeotropic phase-non-uniform phase). These transitions can be of first or of second order depending on the carbon nanotubes segregation intensity.
我们提出了一种关于向列型液晶中碳纳米管悬浮液在外加磁场作用下取向相变的连续统理论。结果表明,在磁场中悬浮液可能存在非均匀相和两种不同的均匀相。悬浮液的均匀相因纳米管与液晶基质的取向耦合类型而异(当纳米管沿基质指向矢取向时为平面型,当纳米管垂直于指向矢时为垂面型)。研究表明存在纳米管浓度重新分布的可能性(偏析效应)。通过解析得到了悬浮液均匀相和非均匀相之间取向转变的场。结果表明,当纳米管与基质弱耦合时,磁场会引发折返转变(均匀平面相 - 非均匀相 - 均匀垂面相 - 非均匀相)。根据碳纳米管的偏析强度,这些转变可以是一级的或二级的。