Oya Naoyuki, Yamada Mihoko, Surinwong Sireenart, Kuwamura Naoto, Konno Takumi
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Dalton Trans. 2018 Feb 20;47(8):2497-2500. doi: 10.1039/c7dt04760f.
Treatment of Λ-fac-[Co(d-pen-N,S)] (d-Hpen = d-penicillamine) with Cu in water gave a stable CoCu complex, ΛΛ-[CoCu(d-pen)] ([1]), having three thiolato-copper(i)-thiolato moieties that bridge two cobalt(iii) centres. Complex [1] was isolated as a coordination polymer of Na[1], which was converted to a complex salt of [Cr(HO)][1] by treatment with Cr(NO).
在水中用铜处理Λ- fac -[Co(d - pen - N,S)]（d - Hpen = d - 青霉胺）得到一种稳定的钴铜配合物，ΛΛ-[CoCu(d - pen)]（[1]），它具有三个桥连两个钴(III)中心的硫醇铜(I)-硫醇基团。配合物[1]以Na[1]的配位聚合物形式分离出来，通过用Cr(NO)处理将其转化为[Cr(HO)][1]的复盐。
