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微波-水热法处理葡萄皮作为一种高效的亚甲基蓝吸附剂。

Microwave-Hydrothermal Treated Grape Peel as an Efficient Biosorbent for Methylene Blue Removal.

机构信息

Department of Industry and Academy Collaborative Development, Xiamen University of Technology, 600 Ligong Road, Jimei District, Xiamen 361024, China.

Fujian Provincial Key Laboratory of Functional Materials and Applications, Institute of Advanced Energy Materials, School of Materials Science and Engineering, Xiamen University of Technology, 600 Ligong Road, Jimei, Xiamen 361024, China.

出版信息

Int J Environ Res Public Health. 2018 Jan 31;15(2):239. doi: 10.3390/ijerph15020239.

DOI:10.3390/ijerph15020239
PMID:29385041
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5858308/
Abstract

Biosorption using agricultural wastes has been proven as a low cost and efficient way for wastewater treatment. Herein, grape peel treated by microwave- and conventional-hydrothermal processes was used as low cost biosorbent to remove methylene blue (MB) from aqueous solutions. The adsorption parameters including the initial pH value, dosage of biosorbents, contact time, and initial MB concentration were investigated to find the optimum adsorption conditions. The biosorbent obtained by microwave-hydrothermal treatment only for 3 min at 180 °C (microwave-hydrothermal treated grape peel, MGP) showed faster kinetics and higher adsorption capability than that produced by a conventional-hydrothermal process (hydrothermal treated grape peel, HGP) with a duration time of 16 h. The maximum adsorption capability of MGP under the optimum conditions (pH = 11, a dosage of 2.50 g/L) as determined with the Langmuir model reached 215.7 mg/g, which was among the best values achieved so far on biosorbents. These results demonstrated that the grape peel treated by a quick microwave-hydrothermal process can be a very promising low cost and efficient biosorbent for organic dye removal from aqueous solutions.

摘要

使用农业废料进行生物吸附已被证明是一种低成本、高效率的废水处理方法。在此,采用微波和常规水热处理的葡萄皮作为低成本生物吸附剂,从水溶液中去除亚甲基蓝(MB)。研究了吸附参数,包括初始 pH 值、生物吸附剂用量、接触时间和初始 MB 浓度,以找到最佳吸附条件。仅在 180°C 下微波水热处理 3 分钟(微波水热处理的葡萄皮,MGP)得到的生物吸附剂比常规水热处理(水热处理的葡萄皮,HGP)得到的生物吸附剂具有更快的动力学和更高的吸附能力,而常规水热处理的持续时间为 16 小时。在最佳条件(pH = 11,用量 2.50 g/L)下用 Langmuir 模型确定的 MGP 的最大吸附能力达到 215.7 mg/g,这是迄今为止在生物吸附剂上获得的最佳值之一。这些结果表明,用快速微波水热处理的葡萄皮可以作为一种很有前途的低成本、高效率的生物吸附剂,用于从水溶液中去除有机染料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/9d1158ad2f51/ijerph-15-00239-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/895ffbfcd988/ijerph-15-00239-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/c86cdf9dc85a/ijerph-15-00239-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/9d1158ad2f51/ijerph-15-00239-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/895ffbfcd988/ijerph-15-00239-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/c86cdf9dc85a/ijerph-15-00239-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5173/5858308/9d1158ad2f51/ijerph-15-00239-g003.jpg

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本文引用的文献

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2
Adsorption of methylene blue on low-cost adsorbents: a review.低价吸附剂对亚甲基蓝的吸附:综述。
J Hazard Mater. 2010 May 15;177(1-3):70-80. doi: 10.1016/j.jhazmat.2009.12.047. Epub 2009 Dec 14.
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Brazil nut shells as a new biosorbent to remove methylene blue and indigo carmine from aqueous solutions.巴西坚果壳作为一种新型生物吸附剂,用于从水溶液中去除亚甲基蓝和靛胭脂。
J Hazard Mater. 2010 Feb 15;174(1-3):84-92. doi: 10.1016/j.jhazmat.2009.09.020. Epub 2009 Sep 11.
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Removal of malachite green from dye wastewater using neem sawdust by adsorption.利用印楝锯末通过吸附作用从染料废水中去除孔雀石绿。
J Hazard Mater. 2009 Aug 15;167(1-3):1089-94. doi: 10.1016/j.jhazmat.2009.01.101. Epub 2009 Feb 6.
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Application of low-cost adsorbents for dye removal--a review.低成本吸附剂在染料去除中的应用——综述
J Environ Manage. 2009 Jun;90(8):2313-42. doi: 10.1016/j.jenvman.2008.11.017. Epub 2009 Mar 4.
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Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass.利用农业废弃生物质蒜皮对水溶液中的亚甲基蓝进行批量吸附。
J Hazard Mater. 2009 May 30;164(2-3):870-5. doi: 10.1016/j.jhazmat.2008.08.084. Epub 2008 Aug 30.
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Grape waste as a biosorbent for removing Cr(VI) from aqueous solution.葡萄废渣作为从水溶液中去除六价铬的生物吸附剂。
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J Hazard Mater. 2008 Feb 11;150(3):703-12. doi: 10.1016/j.jhazmat.2007.05.023. Epub 2007 May 13.
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Adsorption studies on ground shells of hazelnut and almond.对榛子和杏仁磨碎外壳的吸附研究。
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