可见光诱导的苯乙烯氧化双官能化反应：α-三氟甲硫基取代酮的合成
Visible-light-induced oxidative difunctionalization of styrenes: synthesis of α-trifluoromethylthio-substituted ketones.
作者信息
Yadav Arvind Kumar, Singh Krishna Nand
机构信息
Department of Chemistry (Centre of Advanced Study), Institute of Science, Banaras Hindu University, Varanasi-221005, India.
出版信息
Chem Commun (Camb). 2018 Feb 20;54(16):1976-1979. doi: 10.1039/c7cc09953c.
PMID:29400384
Abstract
A novel and practical synthesis of α-trifluoromethylthio-substituted ketones has been accomplished through the visible-light-induced aerobic oxidation of styrenes. The protocol employs the combination of CFSONa and CS as a new source of SCF radicals in the presence of eosin Y as a photoredox catalyst.
摘要
通过可见光诱导的苯乙烯需氧氧化反应，实现了一种新颖且实用的α-三氟甲硫基取代酮的合成方法。该方法采用CFSONa和CS的组合作为SCF自由基的新来源，以曙红Y作为光氧化还原催化剂。
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