Wang Xiuyun, Zhao Weitao, Zhang Tianhua, Zhang Yongfan, Jiang Lilong, Yin Shuangfen
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, Fujian 350002, China.
Chem Commun (Camb). 2018 Feb 22;54(17):2154-2157. doi: 10.1039/c8cc00023a.
We report a new strategy for the design and construction of CoMnO for CH oxidation, a representative VOC. The nanostructures of CoMnO can be tuned from nanowires to needles, hollow/hierarchical microspheres and nanocubes. Moreover, different nanostructures of CoMnO show diverse textural/structural/surface properties, which in turn show strikingly different catalytic performances. Benefitting from its unique structural feature, nanocubic MnO exhibits a superior to considerably high activity for CH oxidation at low temperatures.
我们报道了一种用于设计和构建用于氧化甲烷(一种典型的挥发性有机化合物)的CoMnO的新策略。CoMnO的纳米结构可以从纳米线调整为针状、中空/分级微球和纳米立方体。此外,CoMnO的不同纳米结构表现出不同的织构/结构/表面性质,进而表现出截然不同的催化性能。得益于其独特的结构特征,纳米立方MnO在低温下对甲烷氧化表现出优异至极高的活性。