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通过在超声作用下碳与α-二醇及氢氧化钠的多相反应选择性合成富勒烯稠合二氧六环加合物。

A selective synthesis of the fullerene-fused dioxane adduct via heterogeneous reaction of C with α-diols and NaOH under ultrasonication.

作者信息

Kinzyabaeva Zemfira S, Sharipov Glus L

机构信息

Laboratory of High Energy Chemistry and Catalysis, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Prospekt Oktyabrya, Ufa 450075, Russia.

Laboratory of High Energy Chemistry and Catalysis, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Prospekt Oktyabrya, Ufa 450075, Russia.

出版信息

Ultrason Sonochem. 2018 Apr;42:119-123. doi: 10.1016/j.ultsonch.2017.11.012. Epub 2017 Nov 8.

Abstract

A novel ultrasonic-mediated approach to the synthesis of 1,9-dihydro[C-I]5,6fullerene based on the heterogeneous reaction of fullerene with α-diols and NaOH has been developed. It allows producing the fullerene derivatives with high yields and selectivity.

摘要

一种基于富勒烯与α-二醇和氢氧化钠的多相反应,通过新型超声介导方法合成1,9-二氢[C-I]5,6富勒烯的方法已被开发出来。它能够以高产率和选择性制备富勒烯衍生物。

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