具有丰富的内孔中孔和优异的 MTO 性能的分级 SAPO-34 沸石的经济高效合成。
Cost-effective synthesis of hierarchical SAPO-34 zeolites with abundant intracrystalline mesopores and excellent MTO performance.
机构信息
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.
出版信息
Chem Commun (Camb). 2018 Apr 10;54(30):3697-3700. doi: 10.1039/c8cc00326b.
Hierarchical SAPO-34 catalysts with abundant intracrystalline mesopores have been prepared using morpholine as the template combined with a cheap nonsurfactant cationic surfactant. Significantly, the hierarchical SAPO-34 catalysts exhibit more than 5-fold improved lifetime and 12% enhanced selectivity for ethylene and propylene compared to conventional microporous counterparts in methanol-to-olefin (MTO) reactions.
采用吗啉作为模板剂，结合一种廉价的非表面活性剂阳离子表面活性剂，制备了具有丰富内孔中孔的分级 SAPO-34 催化剂。显著地，与传统的微孔对应物相比，在甲醇制烯烃（MTO）反应中，分级 SAPO-34 催化剂的寿命提高了 5 倍以上，乙烯和丙烯的选择性提高了 12%。
Zotero 插件