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Rational selection of the cation of an ionic liquid to control the reaction outcome of a substitution reaction.

作者信息

Hawker Rebecca R, Haines Ronald S, Harper Jason B

机构信息

School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.

出版信息

Chem Commun (Camb). 2018 Feb 27;54(18):2296-2299. doi: 10.1039/c8cc00241j.

DOI:10.1039/c8cc00241j
PMID:29443346
Abstract

A range of ionic liquids was examined as solvents for a substitution reaction. They were chosen through rationally varying the ionic liquid cation in order to enhance the rate constant. Access to charge and electron-withdrawing substituents benefitted rate enhancement, allowing ionic liquids to be rationally selected to control reaction outcome.

摘要

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