多吡啶氧合铁（IV）配合物对苯甲醛的氧化作用的空间控制及机理：芳香醛的芳香族与苄基羟基化反应
Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes.
作者信息
Turcas Ramona, Lakk-Bogáth Dóra, Speier Gábor, Kaizer József
机构信息
Department of Chemistry, University of Pannonia, H-8201 Veszprém, Hungary.
出版信息
Dalton Trans. 2018 Mar 6;47(10):3248-3252. doi: 10.1039/c7dt03727a.
PMID:29446776
Abstract
The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.
摘要
本研究描述了合成的非血红素氧代铁（IV）配合物对苯甲醛进行羟基化反应的首个实例，其中铁中心的配体环境对反应活性、化学选择性和反应机理有强烈影响。
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