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Al·Ni/SiO₂负载型催化剂上苯乙烯化苯酚合成的研究

A Study on Synthesis of Styrenated Phenol Over Al · Ni/SiO₂-Supported Catalysts.

作者信息

Lee Seungmin, Son Seokhwan, Lee Hyeungen, Kwak Wonbong, Jung Sunghun, Ahn Hogeun, Chung Minchul

机构信息

Department of Chemical Engineering, Sunchon National University, Sunchon-si, Jeollanam-do, 540-742, Korea.

SFC. Co., Ltd., Yeosusandan 1-ro, Yeosu-si, Jeollanam-do, 550-280, Korea.

出版信息

J Nanosci Nanotechnol. 2018 Feb 1;18(2):1461-1464. doi: 10.1166/jnn.2018.14914.

DOI:10.1166/jnn.2018.14914
PMID:29448614
Abstract

Styrenated phenol was prepared by an alkylation of phenol using NiCl2 and AlCl3 supported on silica gel. The conversion of phenol and styrene of alkylation reaction, and the selectivity of styrenated phenol were investigated. The Al · Ni/SiO2 Supported catalyst was used, the conversion of phenol was almost 100%. The product was in the form of a mixture of mono-styrenated phenol, di-styrenated phenol and tri-styrenated phenol. The styrenated phenol were selectivity of the varies depending on the reaction conditions.

摘要

通过使用负载在硅胶上的氯化镍和氯化铝对苯酚进行烷基化反应制备了苯乙烯化苯酚。研究了烷基化反应中苯酚和苯乙烯的转化率以及苯乙烯化苯酚的选择性。使用了Al·Ni/SiO₂负载型催化剂,苯酚的转化率几乎为100%。产物为单苯乙烯化苯酚、二苯乙烯化苯酚和三苯乙烯化苯酚的混合物形式。苯乙烯化苯酚的选择性根据反应条件而变化。

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