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通过中试规模电渗析从废水中回收营养物质。

Nutrient recovery from wastewater through pilot scale electrodialysis.

机构信息

Advanced Water Management Centre, The University of Queensland, St Lucia, QLD, 4072, Australia.

Lappeenranta University of Technology, LUT School of Engineering Science, Skinnarilankatu 34, Lappeenranta, Finland.

出版信息

Water Res. 2018 May 15;135:57-65. doi: 10.1016/j.watres.2018.02.021. Epub 2018 Feb 8.

Abstract

Nutrient recovery performance utilising an electrodialysis (ED) process was quantified in a 30-cell pair pilot reactor with a 7.2 m effective membrane area, utilising domestic anaerobic digester supernatant, which had been passed through a centrifuge as a feed source (centrate). A concentrated product (NH-N 7100 ± 300 mg/L and K 2490 ± 40 mg/L) could be achieved by concentrating nutrient ions from the centrate wastewater dilute feed stream to the product stream using the ED process. The average total current efficiency for all major cations over the experimental period was 76 ± 2% (NH-N transport 40%, K transport 14%). The electrode power consumption was 4.9 ± 1.5 kWh/kgN, averaged across the three replicate trials. This value is lower than competing technologies for NH-N removal and production, and far lower than previous ED lab trials, demonstrating the importance of pilot testing. No significant variation in starting flux densities and cell resistance voltage for subsequent replicate treatments indicated effective cleaning procedures and operational sustainability at treatment durations of several days. This study demonstrates that ED is an economically promising technology for the recovery of nutrients from wastewater.

摘要

利用 30 对 7.2 平方米有效膜面积的电渗析(ED)过程,对经过离心机过滤的国内厌氧消化上清液(浓缩液)作为进料源,对 ED 过程的养分回收性能进行了量化。通过将浓缩液废水中的养分离子浓缩到产品流中,可以得到浓度为 NH-N7100±300mg/L 和 K2490±40mg/L 的浓缩产品。在整个实验期间,所有主要阳离子的平均总电流效率为 76±2%(NH-N 传输 40%,K 传输 14%)。在三个重复试验中,电极的电力消耗平均为 4.9±1.5kWh/kgN。与 NH-N 去除和生产的竞争技术相比,该值较低,与之前的 ED 实验室试验相比,该值低得多,表明了中试的重要性。随后重复处理的起始通量密度和单元电阻电压没有明显变化,表明在数天的处理时间内,清洗程序有效且具有可持续的操作。本研究表明,ED 是从废水中回收养分的一种经济有前途的技术。

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