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通过静电纺丝制备用于超级电容器的生物质基碳纳米纤维

Biomass-Based Carbon Nanofibers Prepared by Electrospinning for Supercapacitor.

作者信息

Zhang Ying-Qiang, Shi Gao-Feng, Chen Bo, Wang Guo-Ying, Guo Tai-Chun

机构信息

School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China.

出版信息

J Nanosci Nanotechnol. 2018 Aug 1;18(8):5731-5737. doi: 10.1166/jnn.2018.15423.

Abstract

Biomass-based carbon nanofibers were prepared by double-nozzle electrospinning the aqueous solution of acid treated the waste medicine Aconitum sinomontanum Nakai extraction and poly-acrylonitrile followed by thermal treatment in an inert atmosphere. The structural, constituent and surface properties of biomass-based carbon nanofibers were investigated by means of spectroscopic, microscopy, energy spectrometer and Brunauer-Emmet-Teller (BET) techniques. The results showed that the biomass-based carbon nanofibers had abundant pore structure and large specific surface area. The electrochemical performance of supercapacitor electrodes with the nanofibers was studied. This electrode showed a capacitance of 295 F/g at the current density of 1 A/g in 6 mol/L aqueous KOH electrolyte, and 98.5% capacity retention after 1000 charge/discharge cycles at the current density of 2 A/g. This indicate that the activate biomass-based carbon nanofibers have a good electrochemical stability.

摘要

通过双喷嘴静电纺丝法制备了基于生物质的碳纳米纤维,该方法是先将经酸处理的中药草乌提取物水溶液与聚丙烯腈进行静电纺丝,然后在惰性气氛中进行热处理。借助光谱、显微镜、能谱仪和布鲁诺尔-埃米特-泰勒(BET)技术对基于生物质的碳纳米纤维的结构、成分和表面性质进行了研究。结果表明,基于生物质的碳纳米纤维具有丰富的孔结构和较大的比表面积。研究了用该纳米纤维制成的超级电容器电极的电化学性能。在6mol/L的KOH水溶液电解质中,该电极在电流密度为1A/g时的电容为295F/g,在电流密度为2A/g下进行1000次充放电循环后容量保持率为98.5%。这表明活化的基于生物质的碳纳米纤维具有良好的电化学稳定性。

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