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呈现单离子磁体行为的五角双锥Ln(III)配合物：一种用于刚性赤道平面的合理合成方法。

Pentagonal-Bipyramid Ln(III) Complexes Exhibiting Single-Ion-Magnet Behavior: A Rational Synthetic Approach for a Rigid Equatorial Plane.

作者信息

Bar Arun Kumar, Kalita Pankaj, Sutter Jean-Pascal, Chandrasekhar Vadapalli

机构信息

School of Chemical Sciences , National Institute of Science Education and Research, Homi Bhabha National Institute , Bhubaneswar 752050 , India.

LCC CNRS , 205 Route de Narbonne , Toulouse F-31077 , France.

出版信息

Inorg Chem. 2018 Mar 5;57(5):2398-2401. doi: 10.1021/acs.inorgchem.8b00059. Epub 2018 Feb 20.

DOI:10.1021/acs.inorgchem.8b00059
PMID:29461817
Abstract

A pentadentate chelating ligand is employed for the facile synthesis of air-stable pentagonal-bipyramid Ln(III) complexes with a rigid equatorial plane. The Dy(III) analogue exhibits single-ion-magnet behavior with U/ k = 70 K under H = 500 Oe.

摘要

一种五齿螯合配体被用于简便合成具有刚性赤道平面的空气稳定的五角双锥Ln(III)配合物。Dy(III)类似物在H = 500 Oe下表现出单离子磁行为，U/k = 70 K。

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